Page 1/13

FRAGOLTHERM Q-32-N

SAFETY DATA SHEET

SECTION 1 : Identification of the substance/mixture and of the company undertaking THIS PRODUCT IS NOT A DANGEROUS SUBSTANCE, AND THEREFORE, UNDER ARTICLE 31 OF THE REACH REGULATION, THERE IS NO LEGAL OBLIGATION TO CREATE A SAFETY DATA SHEET. THIS DOCUMENT IS A VOLUNTARY AND SUPPLEMENTARY SERVICE TO PROVIDE GENERAL SAFETY INSTRUCTIONS IT IS AVAILABLE IN GERMAN AND ENGLISH.

1.1 Product Identification Description of the substance Registration number (REACH) EG-Number CAS-Number

FRAGOLTHERM Q-32-N 01-2119488706-23-xxxx 265-090-8 64741-88-4

1.2 Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Uses advised against

Heat transfer fluid Do not use for private (household) purposes

1.3 Details of the supplier that provides the safety data sheet FRAGOL GmbH+Co. KG Solinger Straße 16 D-45481 Mülheim Deutschland Telephone: +49 (0)208-300 02-50 Fax: +49 (0)208-300 02-33 e-Mail: [email protected] Website: www.fragol.de E-mail (knowledgeable person)

[email protected]

1.4 Emergency number Emergency information service

+49 (0)208-300 02-50 This number is only available during the following service hours: Mon-Fri 09:00 to 17:00

SECTION 2 : Hazard Identification 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 (CLP) This substance does not meet the criteria for classification according to Regulation No 1272/2008 / EC. Additional information According to the results of its assessment, this substance is neither a PBT nor a vPvB substance.

Page 2/13

FRAGOLTHERM Q-32-N

SAFETY DATA SHEET

2.2 Label elements Labeling according to Regulation (EC) No 1272/2008 (CLP) Labeling: not mandatory

2.3 Other dangers without meaning Results of PBT and vPvB assessment According to the results of its assessment, this substance is neither a PBT nor a vPvB substance.

SECTION 3 : Composition / information on ingredients 3.1 Substance Substance name Identification REACH Reg.-Nr. CAS-Nr. EG-Nr. Index-Nr.

Distillate (petroleum), solvent refined heavy paraffinic Base oil (IP 346 <3%,> 20.5 mm2 / s @ 40 ° C) 01-2119488706-23-xxxx 64741-88-4 265-090-8 649-454-00-7

SECTION 4 : First aid measures 4.1 Description of first aid measures General Remarks Do not leave affected persons unattended. Remove the injured person from the danger zone. Keep affected persons quietly, cover and keep warm. Take off dirty, soaked clothes immediately. In case of complaints or in case of doubt, seek medical advice. In case of unconsciousness use stable sides and do not give anything by mouth.

After inhalation Ensure fresh air. In case of irregular breathing or respiratory arrest, immediately seek medical assistance and initiate first aid measures.

After contact with the skin Remove contaminated clothing. In case of contact with skin, wash immediately with plenty of water and soap.

After contact with eyes Remove contact lenses if possible. Rinse thoroughly. Keep eyelids open and rinse thoroughly with clean running water for at least 15 minutes.

After ingestion by ingestion Immediately rinse mouth and drink plenty of water. DO NOT induce vomiting.

Page 3/13

FRAGOLTHERM Q-32-N

SAFETY DATA SHEET

4.2 Most important symptoms and effects, both acute and delayed No symptoms and effects are known to date.

4.3 Indication of any immediate medical attention and special treatment needed Symptomatic treatment. In case of vomiting, observe the risk of aspiration.

SECTION 5 : Fire-fighting measures 5.1 Extinguishing Media Suitable extinguishing media Water spray, alcohol-resistant foam, dry powder, carbon dioxide (CO2)

Unsuitable extinguishing media Water in full beam.

5.2 Special hazards arising from the substance or mixture Hazardous combustion products In case of fire, hazardous fumes / fumes can be produced, nitrogen oxides (NOx), carbon monoxide (CO), carbon dioxide (CO2)

5.3 Instructions for fire fighting Do not inhale explosion gases or combustion gases. Adjust the fire fighting measures to the surroundings. Do not allow fire fighting water to enter drains and waterways. Collect contaminated fire fighting water separately. Fire fighting with appropriate precautions at a reasonable distance.

Special protective equipment for fire fighting Self-contained breathing apparatus (self-contained breathing apparatus, EN 133). Standard protective clothing for the fire brigade.

SECTION 6 : Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Non-emergency personnel Keep people safe. Ventilate affected area.

Operational Forces In case of exposure to vapors, dusts, aerosols and gases wear respiratory protection. Wear suitable protective gloves and protective clothing.

Page 4/13

FRAGOLTHERM Q-32-N

SAFETY DATA SHEET

6.2 Environmental precautions Prevent entry into sewers or surface and ground water. Remove contaminated water and dispose of it.

6.3 Methods and materials for retention and cleaning Notes such as spilled materials can be prevented from spreading. Cover the sewers.

Instructions such as cleaning in case of spillage can occur. Wash with absorbent material (e.g., rags, fleece). Absorb spills. Absorbent substances (sand, silica gel, acid binding agent, universal binder, sawdust, etc.).

Suitable restraint techniques Use of adsorbing materials.

Further information on spillage and release. Dispose of in suitable containers for disposal. Ventilate affected area.

6.4 Reference to other sections Hazardous combustion products: see section 5. Personal protective equipment: see section 8. Incompatible materials: see section 10. Disposal considerations: see section 13.

SECTION 7 : Handling and Storage 7.1 Precautions for safe handling Recommendations Maßnahmen zur Verhinderung von Bränden sowie von Aerosol- und Staubbildung. Verwendung einer örtlichen und generellen Lüftung. Nur in gut gelüfteten Bereichen verwenden. Maßnahmen gegen elektrosta- tische Entladungen treffen. Kann bei Verwendung explosionsfähige/entzündbare Dampf/Luft-Gemische bilden.

Information on general hygiene in the workplace. Wash hands after use. Do not eat, drink or smoke in areas where work is being carried out. Be sure to dispose of contaminated clothing and protective equipment before handling areas where food is eaten. Do not store food or drinks with chemicals. Do not use chemicals that are usually intended for the ingestion of food. Keep away from food, drink and animal feed.

7.2 Conditions for safe storage, including any incompatibilities Meeting the risks of the following kind - hazards caused by flammability Keep away from sources of ignition - No smoking. Take measures against electrostatic discharges.

FRAGOLTHERM Q-32-N

Page 5/13

SAFETY DATA SHEET

- Incompatible substances or mixtures Observe the assembly notes.

Control of effects Protect against external effects, such as Heat. High temperatures. UV radiation / sunlight. Static discharges.

Observe other information Keep in a well-ventilated place. Keep container tightly closed. - special requirements for storage rooms or containers - Storage Temperature Recommended storage temperature: -5 - 40 ° C

7.3 Specific end use(s) No additional information is available.

SECTION 8 : Exposure controls / personal protection equipment 8.1 Parameters to be monitored National limits No information available.

Relevant DNEL / DMEL / PNEC and other thresholds Relevant PNEC and other thresholds

End point

Threshold

Organism

Environmental Compartment

Exposure Time

PNEC

9,33 mg/kg

Aquatic organisms

Water

Short-term (one-off)

8.2 Limitation and monitoring of exposure Suitable technical control devices. General ventilation. Individual protective measures (personal protective equipment)

Eye / face protection. Use protective goggles with side protection (EN 166).

Skin Protection Protective clothing (EN 340).

Page 6/13

FRAGOLTHERM Q-32-N

SAFETY DATA SHEET

- Hand Protection Wear suitable protective gloves. A chemical protective glove approved according to EN 374 is suitable. When dealing with chemical substances, chemical protective gloves must be worn with a CE mark including a fourdigit test number. It is recommended to check the chemical resistance of the above-mentioned protective gloves for specific applications with the glove manufacturer. CAUTION: Wear of moisture-proof gloves (occlusion) longer than 4 hours is defined as a risk in Germany.

- Type of material FKM: fluoroelastomer, fluoro carbon rubber. PVA: polyvinyl alcohol. Nitrile.

- Breakthrough time of the glove material > 480 minutes (permeation level: 6).

- Other protective measures To restore skin regeneration. Preventive skin protection (protective creams / ointments) is recommended. Wash thoroughly after handling.

Respiratory Protection In case of insufficient ventilation, wear respiratory protection. Type: A-P2 (combination filter for particles and organic gases and vapors, identification colors: blue / white). Respiratory protection only with aerosol or mist formation.

Limiting and monitoring the environmental position. To avoid environmental contamination use a proper container. Prevent entry into sewers or surface and ground water.

SECTION 9 : Physical and Chemical Properties 9.1 Information on basic physical and chemical properties Appearance Physical state

liquid

Colour

light yellow

Odor

characteristic

Other safety features PH value

not determined

Melting point / freezing

not determined

Initial boiling point and boiling range

322,7 - 477,8 °C (ASTM D-2887)

Page 7/13

FRAGOLTHERM Q-32-N

SAFETY DATA SHEET

Flash point

>200 °C (ASTM D 92)

Evaporation rate

not determined

Flammability (solid, gaseous)

not relevant (liquid)

Explosion limits

not determined

Vapor pressure

not determined

Density

0,86 - 0,9 kg/l bei 20 °C (ASTM D 4052)

Vapor density

no information available

Solubility (s) - Water solubility

insoluble

Partition coefficient - n-octanol / water (log KOW)

no information available

Auto-ignition temperature

not determined

Viscosity - kinematic viscosity

28,51 mm²/s bei 40 °C 4,5 - 5,5 cSt bei 100 °C (ASTM D 445)

Explosive properties

No

Oxidizing properties

No

9.2 Other Information Without meaning.

SECTION 10 : Stability and Reactivity 10.1 Reactivity This material is not reactive under normal ambient conditions.

FRAGOLTHERM Q-32-N

Page 8/13

SAFETY DATA SHEET

10.2 Chemical stability The material is stable under normal ambient conditions and under the temperature and pressure conditions expected during storage and handling.

10.3 Possibility of hazardous reactions Vapors are heavier than air, spread on the ground and form an explosive mixture with air.

10.4 Conditions to avoid Keep away from heat, hot surfaces, sparks, open flames, and other sources of ignition. Do not smoke.

Physical loads which can lead to a hazardous situation and should therefore be avoided: Strong shocks

10.5 Incompatible materials Oxidant. Combustible materials.

10.6 Hazardous decomposition products Hazardous decomposition products resulting from the use, storage, spillage and heating are not known. Hazardous combustion products: see section 5.

SECTION 11 : Toxicological information 11.1 Information on toxicological effects Classification according to GHS (1272/2008 / EC, CLP) This substance does not meet the criteria for classification according to Regulation No 1272/2008 / EC.

Acute Toxicity Is not classified as acute toxic. May be harmful if swallowed. May be harmful if skin is in contact with skin.

Acute Toxicity Exposure

Endpoint

Value

Species

oral

LD50

>5.000 mg/kg

Rat

inhalation: Dust / Mist

LC50

2,18 mg/l/4h

Rat

dermal

LD50

>2.000 mg/kg

Rabbit

Skin corrosion / irritation Is not classified as skin irritant / irritant.

Serious eye damage / eye irritation Is not to be classified as severe eye damage or eye irritation. OECD Guideline 405.

FRAGOLTHERM Q-32-N

Page 9/13

SAFETY DATA SHEET

Respiratory or skin sensitization Is not classified as an inhalation or skin allergy. OECD Guideline 406.

Germ cell mutagenicity Is not classified as germ cell mutagen.

Carcinogenicity Is not classified as a carcinogen. This product contains mineral oils which are considered highly refined and are not considered carcinogenic according to IARC. The IP 346 test has shown that all of the oils contained in this product contain less than 3% extractable substances.

Reproductive toxicity Is not classified as toxic to reproduction.

Specific target organ toxicity for single exposure Is not classified as specifically target-toxic (single exposure).

Specific target organ toxicity on repeated exposure Is not classified as specifically target-toxic (repeated exposure).

Aspiration Is not classified as aspiration dangerous.

SECTION 12 : Environmental Information 12.1 Toxicity According to 1272/2008 / EC: Not classified as hazardous to waters. Water hazard class: 1, slightly hazardous to water (Germany)

(Acute) Aquatic Toxicity Exposure Time

Endpoint

Value

Species

LL50

>100 mg/l

Fish

96 h

EL50

>10.000 mg/l

Invertebrate aquatic organisms

48 h

Endpoint

Value

Species

Exposure Time

LL50

>10.000 mg/l

EL50

>10.000 mg/l

(Chronic) Aquatic Toxicity

Invertebrate aquatic organisms Invertebrate aquatic organisms

24 h 24 h

FRAGOLTHERM Q-32-N

Page 10/13

SAFETY DATA SHEET

12.2 Persistence and degradability The fabric is easily biodegradable.

12.3 Bioaccumulative No bioaccumulation potential.

12.4 Mobility in the ground There are no data available.

12.5 Results of PBT and vPvB assessment According to the results of its assessment, this substance is neither a PBT nor a vPvB substance.

12.6 Other adverse effects There are no data available.

Potential for endocrine disruption Not listed.

SECTION 13 : Disposal Considerations 13.1 Waste treatment methods Information relevant for wastewater disposal Do not empty into drains. Avoid release to the environment.

Waste treatment of containers / packages Contaminated packaging should be treated as the substance.

Remarks Please observe the relevant national or regional regulations. Waste must be separated so that it can be treated separately from the municipal or national waste disposal facilities.

SECTION 14 : Transport Information 14.1 UN-Number 14.2 UN proper shipping name 14.3 Transport hazard class Class

14.4 Packaging Group 14.5 Environmental hazards 14.6 Special precautions for user

is not subject to transport regulations not relevant not relevant

No additional information is available.

14.7 Transport in bulk according to Annex II of the MARPOL Convention and the IBC Code Not applicable.

FRAGOLTHERM Q-32-N

Page 11/13

SAFETY DATA SHEET

Data according to the UN model regulations Transport of dangerous goods by road, rail or inland waterways (ADR / RID / ADN) Not subject to ADR, RID and ADN regulations.

International Code for the Transport of Dangerous Goods by Sea (IMDG) Not subject to IMDG regulations.

International Civil Aviation Organization (ICAO-IATA / DGR) Not subject to ICAO IATA regulations.

SECTION 15 : Legislation 15.1 Safety, health and environmental regulations / legislation specific for the substance or mixture Relevant provisions of the European Union (EU) Restrictions according to REACH, Annex XVII Not listed.

List of substances subject to authorization (REACH, Annex XIV) Not listed. No ingredient is listed.

National regulations (Germany) Administrative Provisions Water Hazardous Substances (VwVwS) Water hazard class (WGK)

1 slightly hazardous to the aquatic environment Classification according to Annex 3 / Annex 4 (VwVwS)

Storage of hazardous substances in transportable containers (TRGS 510) (Germany) Storage class (LGK)

10 (flammable liquids)

15.2 Chemical Safety Assessment No substance safety assessment has been carried out by the supplier for this substance.

FRAGOLTHERM Q-32-N

Page 12/13

SAFETY DATA SHEET

SECTION 16 : Other Information Abbreviations and Acronyms AbAc

Descriptions of abbreviations used

ADN

(European Agreement on the International Carriage of Dangerous Goods on Inland Waterways)

ADR

Accord européen relatif au transport international des marchandises dangereuses par route (European Convention on the International Carriage of Dangerous Goods by Road)

CAS

Chemical Abstracts Service (database of chemical compounds and their unique key, the CAS Registry Number)

CLP

Regulation (EC) No 1272/2008 on the classification, labeling and packaging of substances and mixtures

DGR

Dangerous Goods Regulations Regulations for the transport of dangerous goods, see IA-TA / DGR

DMEL

Derived Minimal Effect Level (Derived Exposure Level with Minimum Impact)

DNEL

Derived No-Effect Level (derived exposure level without impairment)

EG-Nr.

The EC (EINECS, ELINCS and NLP) index is the source for the seven-digit EC number as a measure for substances in the EU (European Union)

EINECS

European Inventory of Existing Commercial Chemical Substances (European Inventory of Chemical Substances on the Market)

ELINCS

European List of Notified Chemical Substances (European List of Notified Chemical Substances)

GHS IATA IATA/DGR

"Globally Harmonized System of Classification and Laboratory of Chemicals", "Globally Harmonized System for the Classification and Labeling of Chemicals", developed by the United Nations International Air Transport Association (International Air Transport Association) Dangerous Goods Regulations (DGR) for the air transport (IATA) (Rules on the transport of dangerous goods by air)

ICAO

International Civil Aviation Organization

IMDG

International Maritime Dangerous Goods Code (international code for the transport of dangerous goods by seagoing vessels)

Index-Nr. LGK MARPOL

the index number is the identification code indicated in Annex VI, Part 3, to Regulation (EC) No 1272/2008 Storage class according to TRGS 510, Germany International Convention for the Prevention of Pollution from Ships (Abbr. "Marine Pollutant")

NLP

No-Longer polymer (non-longer polymer)

PBT

Persistent, Bioaccumulative and Toxic

PNEC

Predicted No-Effect Concentration (estimated non-effect concentration)

REACH

Registration, Evaluation, Authorization and Restriction of Chemicals (Registration, Evaluation, Authorization and Restriction of Chemicals)

RID

Regulations concerning the International Carriage of Dangerous Goods by Rail (Ordnung für die inter- national Eisenbahnbeförderung gefährlicher Güter)

TRGS

Technical Rules for Hazardous Substances (Germany)

vPvB

very Persistent and very Bioaccumulative (very persistent and very bioaccumulative)

Page 13/13

FRAGOLTHERM Q-32-N

SAFETY DATA SHEET

Important Literature and Data Sources Regulation (EC) No 1272/2008 on the classification, labeling and packaging of substances and mixtures. Regulation (EC) No 1907/2006 (REACH), as amended by Directive 2015/830 / EU. Transport of dangerous goods by road, rail or inland waterways (ADR / RID / ADN). International Code for the Transport of Dangerous Goods by Sea (IMDG). Dangerous Goods Regulations (DGR) for the air transport (IATA) (Rules for the transport of dangerous goods by air).

Disclaimer This information is based on our current knowledge. This SDS was compiled exclusively for this product and is intended exclusively for this product.