Naming Acids What makes an acid unique and how are acids named?

Why? A variety of acids are used in foods, industry, and research. Acids are covalently bonded molecules, but when they are put into water they produce ions. One of the ions produced is always H+, which immediately combines with a water molecule to form the hydronium ion (H3O+). The H3O+ ion is what defines the acidic properties of a substance. Because of their special classification, acids have a naming system different from ionic or other molecular (covalent) compounds.

Model 1 – Binary Acids Acid

Name of acid in aqueous solution

HCl

Hydrochloric acid

HBr

Hydrobromic acid

H2S

Hydrosulfuric acid

HF

Hydrofluoric acid

Cation (+)*

Anion (–)

H3O+

Cl1–

2H3O+

S2–

*Hydrogen ions (H+) join with water molecules in solution to form hydronium ions, H3O+.

1. Complete the cation and anion columns of the table in Model 1. Be careful to show the charges on the ions. 2. Why does hydrosulfuric acid contain two hydrogens? 3. Look at the formulas and names of the binary acids in Model 1. a. What prefix is used at the beginning of the name for all binary acids? b. What suffix is used at the end of the name for all binary acids? 4. The prefix “bi” means “two.” Propose a reason that the acids in Model 1 are all referred to as “binary” acids. 5. Write a rule for naming binary acids.

Naming Acids

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Model 2 – Ternary Acids (Oxyacids) Acid

Name of Acid in Aqueous Solution

HClO3 H2SO3 H2SO4 H3PO3 H3PO4 HNO3 HNO2 H2CO3

Chloric acid Sulfurous acid Sulfuric acid Phosphorous acid Phosphoric acid Nitric acid Nitrous acid Carbonic acid

Polyatomic Anion Polyatomic Anion (–) Name

Cation (+) H3O+

Sulfate Phosphite

H3O

+

PO43– NO21–

Nitrite

6. Look at the formulas of the ternary acids in Model 2. a. How are ternary acids different from binary acids in their structure?

b. What number do you think the prefix “ter-” refers to? 7. When ternary acids are mixed with water, ions will form. Fill in the table above with the formulas and names of the anions. 8. Examine the pairs of ternary acids in Model 2 that contain sulfur, phosphorus, and nitrogen. Each pair has one acid that ends in “-ic” and another that ends in “-ous.” These endings are related to the name of the polyatomic anion found in the acid (“-ate” or “-ite”). Complete the statements below with the correct acid name ending. Polyatomic anion ending is “-ate” → acid name ending is _______. Polyatomic anion ending is “-ite” → acid name ending is _______. 9. If the prefix “hydro-” were used to name a ternary acid, what problem would this create when naming HClO3? 10. Write a rule for naming ternary acids.

11. Predict the formula for chlorous acid. 12. Circle the acid(s) below that would be named beginning with the prefix “hydro-.” H2SO3

2

HF

H2S

H2CO3

HNO2

POGIL™ Activities for High School Chemistry

Extension Questions Model 3 – Halogen Oxyacid Acid Families Acid

Name of Acid

HClO4

Perchloric acid

HClO3

Chloric acid

HClO2

Chlorous acid

HClO

Hypochlorous acid

Cation (+)

Anion (–)

Anion Name Perchlorate

H3O+ Chlorite

HBrO4

Perbromate

HIO3 HFO2 HIO

IO–

Hypoiodite

13. Write the formulas of the cations and anions for each acid in the table in Model 3. 14. Consider the names of the oxyacids in Model 3 that contain chlorine. All halogens form similar oxyacids that use the same naming convention. Fill in the names of the halogen oxyacids to complete the table. 15. The table below includes both binary and ternary acids. Using what you have learned in this activity, fill in the missing formula and name for the anion in each acid, and give the formula of the acid. Acid name

Anion

Anion Name

Acid Formula

Hydroiodic acid Chlorous acid Hypobromous acid Phosphoric acid Sulfurous acid

Naming Acids

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19 Naming Acids-S.pdf

... ternary acids. Using what you have learned in this. activity, fill in the missing formula and name for the anion in each acid, and give the formula. of the acid. Acid name Anion Anion Name Acid Formula. Hydroiodic acid. Chlorous acid. Hypobromous acid. Phosphoric acid. Sulfurous acid. Page 3 of 3. 19 Naming Acids-S.pdf.

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