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Code No: 220853

II-B.Tech. II-Semester Supplementary Examinations, April/May-2004

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CHEMICAL ENGINEERING THERMODYNAMICS (Chemical Engineering) Time: 3 Hours Max. Marks: 70 Answer any FIVE questions All questions carry equal marks --1. A pressure gauge fitted to a steam boiler records a pressure of 34 bar.The vacuum gauge on the condenser indicates 0.94 bar. If the atmospheric pressure is 1 bar , calculate a) Absolute pressure in the boiler in Pa b) Absolute perssure in the condenser in Pa.

Prove that the work interaction in a steady flow process is given by -  Pdv. State clearly the assumptions, if any.

3.

Consider isentropic compression of air from 1.01 bar, 35 C to 5.5 bar. The air is then expanded isobarically to the original volume. Show the processes on the p-v and T-s planes. Also determine the total heat transfer and the total work transfer. Assume the mass of air as 0.75 kg.

4.a) b)

Discuss briefly the virial expansion. Explain briefly the law of corresponding states.

5.

Write briefly about the limitations and real process of second law of thermodynamics.

6.

Calculate the difference in entropy of 0.5kg of liquid water at O C and 1x105 N/m2 pressure and 0.5 kg of water vapor at 100C and 1(atm) pressure. the latent heat of vaporization at 100 C is 530 kgal/kg.

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2.

A process stream is heated as a gas from 25 C to 250 C at constant pressure. A quick estimate of the energy requirement is obtained., with Cp taken as constant and equal to its value at 25 C. Is the estimate of Q likely to be low or high? Why?

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8.

A light fuel oil with an average chemical composition of C10H18 is burning with oxygen in a bomb calorimeter. The heat evolved is measured as 43,960 J / gm for the reaction at 25 C. Calculate the standard heat of combustion of the fuel oil at 25 C with H2O(g) and CO2(g) as products. Note that the reaction in the bomb occurs at constant volume, produces liquid water as a product and goes to completion. -*-*-*-

220853 II-B.Tech. II-Semester Supplementary Examinations, April/May ...

CHEMICAL ENGINEERING THERMODYNAMICS · (Chemical ... Write briefly about the limitations and real process of second law of · thermodynamics.

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