2. a) State sequence Rules. Explain with suitable examples the application of sequence rules in assigning absolute configuration
5
to stereoisomers.
b) How will you distinguish between configuration and conformation ? Discuss the various conformations of cyclohexane and comment on their stabilities.
5
3. a) Predict the product(s) in the following reactions i) (CH3)2CuLi
dryether
+ CH3CH2Br
-CH ii) CH3CH I CH3
~
?
?
= CH2 + HCI
-COOEt -COOEt
iv) CH3 -C =C -CH3
1) OH2)H+ 3) L1-
? CO2
4
-)- ?
2) H2O2/NaOH b) Write short notes on the following i) Baeyer's
s~rain theory
ii)- 1, 2 and 1, 4 addition
:
and its limitations. reactions
6
of alkadienes.
OR
4. a) How do you explain the following ? i) Propene on reaction with HBr in the presence of peroxides yields 1-bromopropane. 1i) 2-bromobutane on dehydrohalogenation as major product.
using alcoholic KOH gives 2-butene
CH3
iii)
I N
CH3
CH2 -CH3
OH on heating
yields ethene
as major
I CH2
CH2 -CH3 6
product and propene as minor product. b) An alkene A having molecular formula C5H10on ozonolysis yields acetone and acetaldehyde as products. Identify the structure of alkene A. c)
How dienes of dienes
?
are classified
? How do you distinguish
between
various
2
classes
2
.
I IIIIII IIIII IIIII IIIII IIIII IIIIIIII
88850
-3-
5. a) Discuss the structure of Benzene in terms of resonance and molecular orbital
7
concepts. b) Explain the mechanism limitations.
of Friedel
crafts alkylation
reaction ,
and mention
its
3 OR 6,
a) Draw energy b) State
profile diagram
Huckel's
non-aromatic
for any electrophilic
rule. Which
of the following
? Offer suitable
explanation
aromatic
substitution
are aromatic,
anti-aromatic
reaction.
4
and
for, each :
~
j) ~ H
ii)O '\--\ iii)
~
iv)
IT rI""1~ d ""=. .Ir-c-
6
-~ 7
a) Discuss and compare the mechanism
of 8N1 and 8N2 reactions of
haloalkanes.
6
b) How do you synthesise the following compounds i)
:
DOT
4
ii) Chloroform OR 8. a) How do you explain the following
?
i) 8N1 reactions are accompanied
by rearraRgement.
4
ii) Allyl chloride is more reactive than Vinyl chloride. b) Giving evidence for the formation of benzyne intermediate, discuss the elimination addition mechanism for nucleophilic
aromation substitution
reaction.
6
.
88850
-4-
9. Answer
any five of the following
i) How will you determine ii) Explain
asymmetric
:
10
the configuration
synthesis
of Geometric
with a suitable
iii) Write a brief note on the acidity iv) What is a regioselective
I IIIIII IIIII IIIII IIIII IIIII IIII IIII
reaction
viii)
Discuss
the addition
of alkynes. ? Explain
substitution
of Friedel-
-elimination
?
example.
with suitable
v) How do you convert benzene into 1, 4-cyclohexadiene mechanism involved. vi) Discuss the mechanism
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