NR

Code No: NR221801

1. (a) Prove the following for a closed system. For constant volume process Q = mCV (T2 − T1 ) For constant pressure process Q = mCP (T2 − T1 )

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II B.Tech II Semester Supplementary Examinations, November/December 2005 THEMODYNAMICS AND KINETICS (Metallurgy & Material Technology) Time: 3 hours Max Marks: 80 Answer any FIVE Questions All Questions carry equal marks ?????

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(b) Differentiate between extensive properties and intensive properties with examples. [12+4] 2. (a) Why the internal energy change in an adiabatic process is negative. Explain. (b) Explain the significance of Joule-Thomson coefficient.

(c) Explain sign conventions of heat and work in thermodynamics.

[5+5+6]

3. (a) State and explain second law of thermodynamics. (b) Define and explain entropy. What are its units. (c) Explain the principle of increase of entropy.

[6+5+5]

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4. (a) What is the entropy criterion for spontaneous change in an isolated system? Give an example of a spontaneous process in an isolated system. (b) Give an equation that relates the entropy change in the surroundings to the enthalpy change in the system. (c) When heat is added to the surroundings, the entropy of the surroundings increases. How does ∆Ssurr depend on the temperature of surroundings? Explain. [5+5+6]

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5. (a) What are the conditions for spontaneous and feasible reactions, in terms of free energies? Explain. (b) Define and discuss the importance of Gibb’s and Helmholtz function.

[8+8]

6. (a) State and explain third law of thermodynamics. What is it’s importance.

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(b) Derive an expression to show variation of equillibrium constant with temperature. [6+10]

7. (a)

i. Does the Clapeyron equation involve any approximation, or is it exact? ii. What approximation are involved in the Clapeyron -clasius equation.

(b) What is Clapeyron equation? What assumptions are made in obtaining the Classius-Clapeyron equation from Clapeyron equation? [8+8]

8. (a) Derive an expression for the rate constant of a first order reaction. 1 of 2

NR

Code No: NR221801

(b) Discuss the importance of equilibrium constant and its effect on equillibrium conversion. [8+8]

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NR221801 II B.Tech II Semester Supplementary Examinations ...

(c) Explain sign conventions of heat and work in thermodynamics. [5+5+6] · 3. (a) State and explain second law of thermodynamics. (b) Define and explain ...

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