USO0RE39986E

(19) United States (12) Reissued Patent

(10) Patent Number: US (45) Date of Reissued Patent:

Reineck et a]. (54)

COATED GROOVING OR PARTING INSERT

(56)

RE39,986 E Jan. 1, 2008

References Cited U.S. PATENT DOCUMENTS

(75) Inventors: Ingrid Reineck, Huddinge (SE); Torbjorn Selinder, Stockholm (SE); Anders Piirhonen, Skarpnack (SE);

4,610,931 A

*

5,336,292 A

Gregor Kullander, Alvsjo (SE)

5,451,469 A 5,545,490 A

*

9/1995

Gustafson et a1. ........ .. 428/548

1/1996 Ostlund et :11. *

5,549,980 A 5,643,658 A 5,652,045 A

Nemeth et a1. ............. .. 75/241

8/1994 Weinl et 31.

5,484,468 A

(73) Assignee: Sandvik Intellectual Property AB, Sandviken (SE)

9/1986

8/1996

Oshika et a1.

............ .. 428/698

8/1996 Ostlund et :11. 7/1997 Uchino et :11. *

7/1997

Nakamura et a1. ........ .. 428/212

(21) App1.No.: 11/449,011

5,674,564 A * 10/1997 Ljungberg et a1.

(22) Filed:

5,789,069 A 5,915,162 A 5,920,760 A

Jun. 8, 2006 Related US. Patent Documents

Issued:

(30)

09/349,106

Filed:

Jul. 8, 1999

(52)

EP EP W0 W0

(SE) ............................................ .. 9802488

Int. Cl. B32B 9/00

0 685 572 B1 0 709 484 B1 WO 97/20082 WO 97/20083

12/1995 5/1996 6/1997 6/1997

Primary ExamineriArchene Turner (74) Attorney, Agent, or FirmiDrinker Biddle & Reath LLP

(57)

(2006.01)

US. Cl. ......................... .. 428/216; 51/307; 51/309;

427/255.1; 427/2553; 427/255.2; 427/368; 427/355; 428/195; 428/323; 428/469; 428/472; 428/698; 428/699; 428/701; 428/702 (58)

Ljungberg et a1. ........ .. 428/216 Uchino et a1. ...... .. 428/698 Yoshimura et a1. ....... .. 428/551

* cited by examiner

Foreign Application Priority Data

Jul. 9, 1998

(51)

6,261,673 Jul. 17, 2001

Appl. No.:

8/1998 6/1999 7/1999

FOREIGN PATENT DOCUMENTS

Reissue of:

(64) Patent No.:

* * *

Field of Classi?cation Search ................. .. 51/307,

51/309; 427/255.1, 255.2, 255.3, 368, 355; 428/216, 323, 195, 469, 472, 698, 699, 701, 428/702

See application ?le for complete search history.

ABSTRACT

The present invention relates to a coated cutting tool insert useful for grooving or severing steel components such as steel or stainless steel tubes and bars. The insert is charac terized by WCiCo-based cemented carbide substrate hav

ing a highly W-alloyed Co-binder phase and a relatively thin coating including an inner layer of TiCxNyOZ With columnar grains followed by a layer of ?ne grained KiAl2O3 and a top layer of TiN. 31 Claims, 1 Drawing Sheet

U S. Patent

Jan. 1, 2008

FIG. 1

US RE39,986 E

US RE39,986 E 1

2 a coating comprising a ?rst innermost layer of TiCxNyOZ Wherein x+y+Z=l,

COATED GROOVING OR PARTING INSERT

the ?rst layer having a thickness of 0.l*l.5 um and

Matter enclosed in heavy brackets [ ] appears in the original patent but forms no part of this reissue speci? cation; matter printed in italics indicates the additions made by reissue.

equiaxed grains With siZe<0.5 um, a second layer of TiCxNyOZ Wherein x+y+Z=l, the second layer having a thickness of 0.4*3.9 mm, preferably l.5*3.0 pm, With coluanar grains With an average diameter of 0150 um, a third layer of a smooth ?ne-grained KiAl2O3 layer

CROSS-REFERENCES T0 RELATED APPLICATIONS

With a thickness of 0.5*5.5 pm, and

The present application is a reissue of US. Pat. No.

the total thickness of the ?rst innermost TiCxNyOZ and the second TiCxNyOZ layer is 0.54.0 pm, and the total thickness of all layers is 2.(%6.0 mm, preferably

6,261, 673 B], which claims the bene?t ofpriority to Swedish Application No. 9802488-8?led Jul. 9, 1998. FIELD OF THE INVENTION

3.0*5.0 pm. 15

The present invention relates to a coated cemented car

bide body. The present invention further relates to a coated

cutting tool insert useful for grooving or severing steel

coating the body by:

components such as steel or stainless steel tubes and bars. 20

BACKGROUND OF THE INVENTION

With a siZe <0.5 pm, 25

ing a thickness of 0.4*3.9 pm and columnar grains

30

On the other hand, for grooving of the same materials, a high coating Wear resistance in combination With a stiff

substrate material is required. Finding a cutting tool material that e?fectively ful?ls both these requirements is a challenge. So far it has been very di?icult to improve all tool

35

properties simultaneously. Commercial cemented carbide

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

45

severing or grooving of steel and stainless steel includes a cemented carbide substrate With a highly W-alloyed binder phase and With a Well balanced chemical composition and

A cutting tool insert according to the invention useful for

carbides coated by one layer of TiCxNyOZ With columnar grains, one layer of smooth, ?ne grained KiAl2O3, and

grain siZe of the WC, a columnar TiCxNyOZ-layer Which layer thickness should be kept as loW as possible, a KiAl2O3-layer, a TiNayer and optionally folloWed by

cutting insert particularly useful for Wet and dry milling of loW and medium alloyed steels. The insert is characterised by a cemented carbide substrate consisting of CoiWC and

cubic carbides, a coating including a layer of TiCxNyOZ With columnar grains, a layer of smooth, ?ne grained KiAl2O3

smoothening the cutting edges. For example, the edges may 50

and preferably an outer layer of TiN. 55

According to the present invention, a combination of the

60

Co in the cemented carbide. The CW-value is a function of the W content in the Co binder phase. A loW CW-value corresponds to a high W-content in the binder phase.

According to the present invention improved cutting per

According to the principles of the present invention, a

cutting tool insert is provided Which comprises:

formance is achieved if the cemented carbide substrate has a CW-ratio of 0.78*0.93.

a cemented carbide body comprising 6*l5 Weight % Co, 0.2il .8 Weight % cubic carbides of With a CW-ratio of 0.78*0.93, and the balance WC; and

CW-ratio=MS(Wt % Co'0.0l6l), Where MS is the measured saturation magnetisation of the cemented carbide substrate in hAm2/kg and Wt % Co is the Weight percentage of

cemented carbide substrates, coatings and insert styles has been developed Which gives rise to excellent cutting per

Ti, Ta and/or Nb, a highly W-alloyed binder phase

be smoothed by brushing, e.g.iby a SiC-based brush. Surprisingly, bene?cial properties have been achieved With a relatively thin coating. The cobalt binder phase is highly alloyed With W. The content of W in the binder phase can be expressed as the

SUMMARY OF THE INVENTION

formance in grooving as Well as severing of steel or stainless steel.

BRIEF DESCRIPTION OF THE DRAWING FIGURES

40

stainless steel components. The inserts are characterised by a cemented carbide body consisting of WCiCo and cubic

preferably an outer layer of TiN. Swedish patent application 9504304-8 discloses a coated

forming a third layer of a smooth KiAl2O3 having a thickness of 0.5*5.5 pm, and forming the layers such that the total thickness of the ?rst and second layers is 0.5*4.0 um, and the total thickness of all layers is 2.(P6.0 pm.

FIG. 1 shoWs in l800>< magni?cation of a cross section of an insert according to the present invention.

grades have therefore been optimised With respect to one or feW of the Wear types and hence to speci?c application areas. Swedish patent application 9602413-8 discloses a coated

cutting insert particularly suited for Wet turning or grooving

forming a second layer of TiCXNyOZ by a MTCVD technique, Wherein x+y+Z=l, the second layer hav With an average diameter of 0.l*5.0 pm,

insert. As a result, the coating can ?ake and small cemented carbide chips can be torn out of the cutting tool or cutting

tool insert substrate body.

forming a ?rst innermost layer of TiCxNyOZ With a

CVD-based technique, Wherein x+y+Z= l, the ?rst layer having a thickness of 0.l*l.5 um and equiaxed grains

When steel or stainless steel tubes or bars are severed

using an appropriate coated cutting tool or cutting tool insert, the cutting edge is frictionally heated to a high temperature With the consequence that the material being cut becomes Welded onto the cutting edge of the cutting tool

Further according to the present invention, a method of making a cutting tool insert comprising a WCiCo-based cemented carbide body With a highly W-alloyed binder phase and a CW-ratio of 0.78%).93, the method comprising

According to the present invention a parting tool insert is 65

provided With a cemented carbide substrate With a compo

sition of 6*l5 Wt % Co, preferably 9*l2 Wt % Co, and most preferably l0ill Wt % Co. The composition further includes

US RE39,986 E 4

3

<5 um, preferably 0.1420 pm, is applied preferably

0.2418 Wt % cubic carbides, preferably 0.4*1.8 Wt % cubic carbides, most preferably 0541.7 Wt % cubic carbides, of the metals Ta, Nb and Ti and balance WC. The cemented carbide may also contain other carbides from elements from group lVb, Vb or Vlb of the periodic table. The content of

using a MTCVD-technique (egiusing acetonitrile as the carbon and nitrogen source for forming the layer in the temperature range of 70049000 C.). The exact conditions, hoWever, depend to a certain extent on the

design of the equipment used;

Ti is preferably on a level corresponding to a technical

impurity. The preferred average grain siZe of the WC depend

the total thickness of the ?rst and second layers is 0.54.0

on the binder phase content. At a preferred composition of 10411 Wt-% Co, the preferred grain siZe is 1.5420 um, most preferably about 1.7 um. The CW-ratio shall be 0.78%).93,

um, preferably 1.5435 um. Preferably, the ?rst layer is thinner than the second layer; a third layer of a smooth, ?ne-grained A1203 consisting essentially of the K-phase having a grain siZe about

preferably 08040.91, and most preferably 08240.90. The cemented carbide may contain small amounts, <1 volume %, of p-phase (M6C), Without any detrimental effect. From the

0542.0 um. The Al2O3-layer has a thickness of 0.5455

um, preferably 0543.0 um. Preferably, this A1203 -layer

CW-value it folloWs that no free graphite is alloWed in the cemented carbide substrate according to the present embodi

is folloWed by a further layer of TiN having a thickness

<1 um, preferably 0.1405 um thick. The A1203 layer

ment.

can be exposed as the outermost layer. The outermost

The coating comprises a ?rst innermost layer of TiCxNyOZ With x+y+Z=1, preferably y>x and Z<0.2, most preferably y>0.8 and Z=0, With equiaxed grains With a siZe <0.5 um, and a total thickness <1.5 pm but >0.1 um, preferably the thickness is 0.1406 pm;

layer of A1203 or TiN has a surface roughness Rmax<0.4 um over a length of 10.0 pm. The smooth coating

surface can be obtained by gently Wet-blasting the 20

a second layer of TiCxNyOZ With x+y+Z=1, preferably With Z=0, x>0.3 and y>0.3, most preferably x>0.5, With

on SiC as disclosed in SWedish patent application

a thickness of 0443.9 um, preferably the thickness is

1543.0 pm, the second layer has columnar grains With

25

an average diameter of <5 um, preferably 0142.0 pm; the total thickness of the ?rst and second layers is 0544.0

um, preferably 1543.5 um. Preferably, the ?rst layer is thinner than the second layer; a third layer of a smooth, ?ne-grained A1203 consisting

coating surface With ?ne grained (4004150 mesh) alu mina poWder, or by brushing (preferably used When TiN top layer is present) the edges With brushes based 9402543-4. The TiN-layer, if present, is preferably removed along the cutting edge; and the total thickness of the ?rst, second and third layers is 2.0460 um, preferably 3.0450 pm. As a Way of further illustrating the present invention and

30

the advantages thereof, the folloWing examples are given.

essentially of the K-phase having a grain siZe about

EXAMPLE 1

0.542 um. HoWever, the layer may contain small

A. A cemented carbide cutting tool insert in style N151 .2 300-5E With the composition 10.5 Wt-% Co, 1.16 Wt-% Ta, 0.28 Wt-% Nb and balance WC, With a binder phase highly alloyed With W corresponding to a CW-ratio of 0.87, Was coated With an innermost 0.5 pm equiaxed TiCO_O5NO_95 layer With a high nitrogen content, corresponding to an estimated C/N ratio of 0.05, folloWed by a 2.2 pm thick layer

amounts, 143 vol-%, of the 0 or the ot-phases as

determined by x-ray diffraction (XRD) measurement. The Al2O3-layer has a thickness of 0.5455 um, pref erably 0543.0 um; preferably, this Al2O3-layer is folloWed by a further layer of TiN having a thickness <1 um, preferably 0.1%).5 pm thick. The A1203 or the TiN layer can be the

35

40

outermost layer. This outermost layer, Whether A1203 or TiN, has a surface roughness Rmax<0.4 um over a

length of 10 um. The TiN-layer, if present, is preferably removed along the cutting edge by a suitable removal technique, such as brushing; and the total thickness of the ?rst, second and third layers is

45

SiC containing nylon straW brush after coating, removing

According to a method of the invention, a WC4Co-based

9412 Wt % Co, and most preferably 10411 Wt % Co. The WC grain siZe is 1542.0 um, most preferably about 1.7 pm, When the Co content is in the 10411 Wt. % range. The body

is coated by: a ?rst innermost layer of TiCxNyOZ With x+y+Z=1, pref erably y>x and Z<0.2, most preferably y>0.8 and Z=0,

50

a thickness of 0443.9 um, preferably 1543.0 pm, with columnar grains and With an average diameter of about

the outer TiN layer on the edge. B. A cemented carbide cutting tool insert in style N151 .2 300-SE With the composition of 8.0 Wt-% Co, no cubic carbides, balance WC and a CW-ratio of 0.94 Was prepared. The insert Was coated With an innermost 0.5 pm equiaxed

TiCN-layer. A 1.5 pm TiN layer Was deposited, during the same cycle, on top of the TiCN-layer. No post treatment Was 55

applied. C. A cemented carbide cutting tool insert in style N151 .2 300-SE With the composition of 8.0 Wt-% Co, no cubic carbides, balance WC and a CW-ratio of 0.94. The insert Was

60

With equiaxed grains With siZe <0.5 um and a total thickness <1.5 um, preferably >0.1 um, preferably 0.1%).6 um, using knoWn CVD-methods;

a second layer of TiCxNyOZ With x+y+Z=1, preferably With Z=0, x>0.3 and y>0.3, most preferably x>0.5, With

a 1.5 um layer of A1203 consisting of pure ic-phase Was formed according to procedure disclosed in EP-A-523 021. A thin, 0.5 pm, TiN layer Was deposited, during the same cycle, on top of the Al2O3-layer. Hence, the total thickness of all layers is 4.7 pm. The coated insert Was brushed by a

246 um, preferably 345 um. cemented carbide substrate is made With a highly W-alloyed binder phase With a CW-ratio of 0.784093, preferably 0.80%).91, and most preferably 0.82%).90. The content of cubic carbides of the metals Ta, Nb and Ti is 0.2418 Wt %, preferably 0.4418 Wt %, and most preferably 0541.7 Wt %. The substrate further includes 6415 Wt % Co, preferably

of columnar TiCoO_54NO_46 deposited using MT-CVD tech nique. In subsequent steps during the same coating process

coated With an innermost 0.5 pm equiaxed TiCN-layer With a high nitrogen content, corresponding to an estimated C/N ratio of 0.05, folloWed by a 4.0 um thick layer of columnar

TiCN deposited using MT-CVD technique. In subsequent 65

steps during the same coating process a 1.0 um layer of A1203 consisting of pure K phase Was formed according to procedure disclosed in EP-A-523-021. A thin, 0.5 um TiN layer Was deposited, during the same cycle, on top of the Al2O3-layer. The coated insert Was brushed by a SiC con

US RE39,986 E 5 taining nylon straw brush after coating, removing the outer TiN layer on the edge. D. A comparative cemented carbide cutting tool insert in

Insert

Number of components

style similar to N151.2-300-5E from an external leading cemented carbide producer Was selected for comparison. A (acc. to invention) 400 D (external grade) 150 The carbide had a composition of 11.0 Wt-% Co, 7.1 Wt-% TiC, 12.1 Wt-% TaC, 1.3 Wt-% NbC, balance WC and a CW-ratio of 0.80. The insert had a coating consisting of 1.1 EXAMPLE 5 pm TiN and, outermost, 0.3 pm TiCN layer. Examination in light optical microscope revealed no edge treatment subse- 10 Inserts A (insert style N151.2-400-4E) and D Were tested quent to coating. at an end users machine shop in parting of a steel bar Inserts from A, B and C Were compared in a ?aking test ($32225, OD 50 mm) With feed 0064114 mm/reV and

comprising a facing operation in austenitic stainless steel (SanMac 304L). Feed 0.15 mm/rev, speed 130 m/min and depth of cut varying betWeen 0*2.5 mm.

15 even ?ank Wear Was seen on insert A.

Number of cuts before extensive

Insmt

speed 180 III/min Insert D failed due to chipping of the cutting edge While

Insert

?aking

A (acc. to invention)

10

B (outside invention)

5

Number of components

20

A (acc. to invention) D (external grade)

300 150

C (Outside iHWHtiOH)

1

While the present invention has been described by refer

D (emmal grade)

3

25 ence to the above-described embodiments, certain modi?

cations and variations Will be evident to those of ordinary skill in the art. Therefore, the present invention is to limited

EXAMPLE 2

only the scope and spirit of the appended claims.

Inserts A, B, C and D from above Were tested in a serving test of stainless steel (882343) in the form of 12 mm bar 30 Stainless steel,

The rotating speed Was 1800 rpm, feed varying 0.15*0.02

6*15 Welght % CO> 0-2’1 ~8 welgm % Cublc carbldés of T1’ Ta, Nb of any comblnatlcfn thereof, 2‘ hlghly

mm/rev (loW feed rate close to centre of bar). The Wear mechanism Was ?aking combined With nose -

What is Claimed is? 1- A cutting tool insert Comprising? a cemented carbide body comprising

w'anoyed bmder phase Wlth a CW'ranO of 35

crack1ng.

0.78%).93, and the balance WC; and _ _ _ a coating comprising

a ?rst innermost layer of TiCxNyOZ Wherein x+y+Z=1,

B (outgid? inv?nt'ion)

180

the ?rst layer having a thickness of 0.1*1.5 um and equiaxed grains With siZe <0.5 pm, a second layer of TiCxNyOZ Wherein x+y+Z=1, the second layer having a thickness of 0.4e3.9 pm, with

0 (outside invention)

200

columnar grains With an average diameter of 0.150

D (external grade)

200

insert A (am to inv?nt)

Number of components 380

40

pm,

a third layer of a smooth ?ne-grained KiAl2O3 layer 45

EXAMPLE 3

Inserts A (insert style N151.2-400-4E) and D Were tested at an end users machine shop in severing of stainless steel

tube ($82343, OD 27 mm’ ID 25 mm) With feed 0'05 mm/rev and Speed 150 m/min~ I

.

.

With a thickness of 0.5*5.5 um, and

a total thickness of the ?rst innermost TiCxNyOZ and the

SeFOnd TICXNyOZ layer_ 15 0'54'0 pm’ and the total thlckn?ss of an_layers 1S 2'(_%6'0 pm‘

_

2. The cutt1ng tool insert of cla1m 1, wherein the body 50 comprises 9*12 Weight % Co and a CW rat1o of 0.80%).91.

.

.

.

nsert D failed due to maJor ch1pp1ng of the cutt1ng edge . . . . Wh1le a very small ch1pp1ng Was seen on insert A.

3. The cutting tool inset of claim 1, Wherein in the ?rst

1 . . ayer y>x and Z<0.2, and the th1ckness of the ?rst layer 1s 0 1%) 6 pm

4. The cutting tool insert of claim 1, Wherein in the second 55 layer Z=0, x>0.3 and y>0.3, the second layer has a thickness 1mm

Number of Components I

I

SW0‘ to invzlzimn) (emma gr 6)

of 1.5*3.0 pm, with the columnar grains having an average diameter of 0.1*2.0 um.

i5;

5. The cutting tool insert of claim 1, Wherein in the third

layer the grains of the KiAl2O3 have a siZe on the order of 60 0.5*2.0 um, and the third layer has a thickness of 0.5e3.0 pm. EXAMPLE 4 6. The cutting tool insert of claim 1, Wherein the total Inserts A and D Were tested at an end users machine shop thickness of the ?rst and second layers is 1.5*3.5 pm. in parting to centre of an annealed high alloy steel SS2242 7. The cutting tool insert of claim 1, Wherein the total With feed 0.15 mmlrev and speed 100 m/min. 65 thickness of all the layers is 3.(%5.0 pm. 8. The cutting insert of claim 1 further comprising an Insert D failed due to cracking in the comers While a very small deformation in the comers Was seen on insert A. outermost layer of TiN having a thickness of 0.1*1.0 um.

US RE39,986 E 8

7 9. The cutting insert of claim 8, wherein the outermost

18. The method of claim 17 Wherein the cemented carbide body has a CW-ratio of 0.82*0.90. 19. The method of claim 14, Wherein the outermost

TiN-layer has been removed along the cutting edge. 10. A method of making a cutting tool insert comprising a WC4Co-based cemented carbide body With a highly

TiN-layer is removed along a cutting edge.

W-alloyed binder phase and a CW-ratio of 0.78%).93, the

20. The method of claim 19, Wherein the outermost

method comprising coating the body by the steps of:

TiN-layer is removed by brushing.

forming a ?rst innermost layer of TiCxNyOZ With a

2]. The cutting tool inset ofclaim 3, wherein in the second layer Z=O, x>O.3 andy>O.3, the second layer has a thickness of].5*3.0 pm with the columnar grains having an average diameter of O.]*2.0 ,um. 22. The cutting tool insert ofclaim 2], wherein in the third layer the grains ofthe K-Al2O3 have a size on the order of O.5*2.0,um and the third layer has a thickness ofO.5i3.0,um. 23. The cutting tool insert ofclaim 22, wherein the total thickness ofall the layers is 3&50 ,um. 24. The cutting insert ofclaim 22 further comprising an outermost layer of TiN having a thickness of O.]*].O ,um. 25. The cutting insert of claim 24, wherein the outermost

CVD-based technique, Wherein X+y+Z= l, the ?rst layer having a thickness of 0.l*l.5 um and equiaxed grains With a siZe <0.5 um,

forming a second layer of TiCxNyOZ by a MTCVD technique, Wherein X+y+Z=l, the second layer having a thickness of 0.4*3.9 um and columnar grains With an average diameter of 0.l*5.0 um, forming a third layer of a smooth K-Al2O3 having a thickness of 0.5*5.5 um, and

forming the layers such that the total thickness of the ?rst and second layers is 0.54.0 um, and the total thickness of all layers is 2.(%6.0 um. 11. The method of claim 10, Wherein the step of forming

20

26. The method ofclaim 1] wherein the step offorming the second layer further comprises using acetonitrile as the

the ?rst layer further comprises providing the ?rst layer With y>x and Z<0.2 and a thickness of 0.l*0.6 um.

12. The method of claim 10 Wherein the step of forming the second layer further comprises using acetonitrile as the carbon and nitrogen source and forming the second layer at a temperature of 850*900° C., the step of forming the second

carbon and nitrogen source andforming the second layer at a temperature of850i900o C., the step offorming the second 25

layer further comprises providing Z=0, X>0.3 and y>0.3, a thickness of l.5*3.0 um, and With the columnar grains having an average diameter of 0.l*2.0 um. 13. The method of claim 10, Wherein the third layer is provided With a thickness of 0.5%.0 um. 14. The method of claim 10, Wherein the method further comprises forming an outer layer of TiN having a thickness of <1 um. 15. The method of claim 10, Wherein the method further

TiN-layer has been removed along the cutting edge.

30

35

layerfurther comprises providing Z=O, x>O.3 and y>O.3, a thickness of ].5*3.0 ,um and with the columnar grains having an average diameter of O.]*2.0 ,um. 27. The method ofclaim 26, wherein the methodfurther comprises forming an outer layer of TiN having a thickness of <1 ,um. 28. The method of claim 27, wherein the outermost TiN-layer is removed along a cutting edge. 29. The method ofclaim 26, wherein the methodfurther comprises providing the first and second layers with a total thickness of].5*3.5 ,um and a total thickness ofall layers of

comprises providing the ?rst and second layers With a total

3.0*5.0 ,um.

thickness of l.5*3.5 um, and a total thickness of all layers of 3.(%5.0 um. 16. The method of claim 10 Wherein the said cemented carbide body has a cobalt content of 9*l2 Weight % and 0.4*l.8 Weight % cubic carbides of Ta and Nb. 17. The method of claim 10 Wherein the cemented carbide body has a cobalt content of 1(Lll Weight %.

30. The method of claim 10 wherein the said cemented carbide body has a cobalt content of 9*]2 weight % and O.4*].8 weight % cubic carbides of Ta and Nb. 3]. The method ofclaim 30 wherein the cemented carbide body has a C W-ratio of O.82*O.90.

40

*

*

*

*

*

Reissued Patent

test of stainless steel (882343) in the form of 12 mm bar 30 1- A cutting tool insert Comprising? ... The rotating speed Was 1800 rpm, feed varying 0.15*0.02.

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into signal point groups to Which data of the ?rst data stream are assigned. Also, data of .... 7, Jul. 1981, pp. 9824989. L. J. Cimini, Jr., “Analysis and Simulation of a Digital ... Digital Television: A RevieW, Multidimensional Systems and Signa

Reissued Patent
(2006.01). 15a. (56). References Cited. U.S. PATENT DOCUMENTS. 1,142,698 A. 6/1915 Grove et 31. 1,191,556 A. 7/1916 Blake. 1,268,544 A. 6/1918 Cates. 1,796,893 A ..... softWare component is preferably less than 50. Examples for the .... end, the bris

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Due to this disadvantage, trans porters presently employed in the related art are sold with replacement seal kits to maintain the proper control of for ward and reversing speed and motion cycle. Replacing seals requires downtime of production process

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5,385,348 A >x< M995 wargo. D482,093 s * 11/2003 Imamoto ................. .. D21/759. 5,421,577 A * 6/1995 Kobayashi. 6,641,487 B1 * 11/2003 Hamburger. 5431401 A ,, M995 Smith. 2002/0137576 A1 * 9/2002 Dammen. 535713053 A ,, “A996 Lane. 2002/01608

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13 May 2005 - infra-red (IR) transceiver, may support data transfers at only a fraction of the speed of which the memory is ... the rate at Which the resource can process data (i.e., the bandwidth of the resource). ...... Claim 33, line 65 please del

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12/1991 Eigler et al. 5,082,935 A. 1/1992 Cruickshank. A. 5,118,605. 6/1992 Urdea. (Continued). FOREIGN PATENT DOCUMENTS. DE. 3930312. * 4/1990. DE. 4011991. * 10/1990. EP. 0217403 A2 10/1986. EP .... Model Determination of (xiAntitrypsin in Human Se

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register address is stored With each data entry, tWo entries in command FIFO ..... register rather than in the index, or some other means such as an I/O pin could ...

Reissued Patent
Nov 20, 2000 - microplate manager/PC data analysis software. Levels of .... mM EDTA, and 0.1% SDS at a concentration of 4 ug/ml and used directly for ...

Reissued Patent
parts An apparatus, method and storage medium for repro ducing digital data, are ... 1) a?rst type ofdigital audio data, and 2) a second type of digital audio data ...

Reissued Patent
Primary ExamineriRober't Chevalier ... recording system, at the time of recording of primary data, ... tion purposes stored in a recording region on a recording.

Reissued Patent
many experimental con?gurations equivalent to up/down wave?eld separation of the recorded data. In such con?gura tions the down-going part of the wave?eld represents the ghost and the up-going wave?eld represents the desired sig nal. Exact ?lters for

Reissued Patent
Baker Oil Tools; FloW Control Systems Technical Unit; Test. Sleeve for Dual FloW .... times, and to inject ?uids such as water into different zones at different times ...

Reissued Patent
Aviv “New on-board data processing approach to achieve large com paction,” SPIE, 1979 .... not reliably monitor the “real-time” images from one or sev eral cameras for ...... depending on the range, through inclement Weather. What is claimed 

Reissued Patent
orthogonal frequency division multiplexed (OFDM) com munication system comprises: a plurality of remote units, a host unit; wherein the host sends an adjustment signal to a remote instructing the remote to adjust the timing of trans missions from the