SAFETY DATA SHEET
Issue Date 05-Jun-2016
Revision Date 06-Jun-2016
SPD PROTECTOR B
SPD Protector Part B
Version 1
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1. IDENTIFICATION Product identifier Product Name
SPD Protector Part B
Other means of identification Product Code
SPD PROTECTOR B
Recommended use of the chemical and restrictions on use Restricted to professional users. Recommended Use Consumer use Uses advised against Details of the supplier of the safety data sheet Supplier Address Manufacturer Address Solomon Colors, Inc. Solomon Colors, Inc. 4050 Color Plant Road 4050 Color Plant Road Springfield, IL Springfield, IL 62702 62702 800-624-0261 (US & Canada); 217-522-3112 (Outside North America) Company Phone Number 24 Hour Emergency Phone Number 800-373-7542
2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Acute toxicity - Oral Acute toxicity - Inhalation (Gases) Acute toxicity - Inhalation (Vapors)
Category 4. Category 4 Category 4
Label elements Emergency Overview Warning
Hazard statements Harmful if swallowed Harmful if inhaled Causes serious eye irritation May cause an allergic skin reaction
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Appearance No information available
Physical state Liquid
Odor Slight, faint ammonia odor
Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Avoid breathing dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a POISON CENTER or doctor/physician if you feel unwell IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell Rinse mouth Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Other Information •Maybehar mf uli ncont actwi t hski n •Har mf ult oaquat i cl i f ewi t hl ongl ast i ngef f ect s •Har mf ult oaquat i cl i f e
3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name Aromatic Alcohol Colloidal Silica Poly-Oxy Amine m-Xylylenediamine Glycol Ether
CAS No. Proprietary Proprietary Proprietary 1477-55-0 Proprietary
Weight-% 5-35 5-25 2-25 5-25 1-15
Trade Secret * * * * *
*The exact percentage (concentration) of composition has been withheld as a trade secret.
4. FIRST AID MEASURES Description of first aid measures Eye contact
Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician.
Skin Contact
Wash skin with soap and water.
Inhalation
Remove to fresh air.
Ingestion
Clean mouth with water and drink afterwards plenty of water.
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Most important symptoms and effects, both acute and delayed Symptoms
No information available.
Indication of any immediate medical attention and special treatment needed Note to physicians
Treat symptomatically.
5. FIRE-FIGHTING MEASURES Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media Caution: Use of water spray when fighting fire may be inefficient. Specific hazards arising from the chemical No information available. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions
Ensure adequate ventilation, especially in confined areas.
Environmental precautions Environmental precautions
See Section 12 for additional ecological information.
Methods and material for containment and cleaning up Methods for containment
Prevent further leakage or spillage if safe to do so.
Methods for cleaning up
Pick up and transfer to properly labeled containers.
7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling
Handle in accordance with good industrial hygiene and safety practice.
Conditions for safe storage, including any incompatibilities Storage Conditions
Keep containers tightly closed in a dry, cool and well-ventilated place.
Incompatible materials
Incompatible with strong acids and bases. Incompatible with oxidizing agents. Chlorinated compounds.
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8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines
.
Chemical Name Colloidal Silica
ACGIH TLV -
m-Xylylenediamine 1477-55-0 Glycol Ether
S* Ceiling: 0.1 mg/m3 STEL: 100 ppm TWA: 50 ppm
OSHA PEL (vacated) TWA: 6 mg/m3 <1% Crystalline silica TWA: 20 mppcf : (80)/(% SiO2) mg/m3 TWA (vacated) S* (vacated) Ceiling: 0.1 mg/m3 (vacated) TWA: 100 ppm (vacated) TWA: 360 mg/m3 (vacated) STEL: 150 ppm (vacated) STEL: 540 mg/m3
NIOSH IDLH IDLH: 3000 mg/m3 TWA: 6 mg/m3
Ceiling: 0.1 mg/m3 TWA: 100 ppm TWA: 360 mg/m3 STEL: 150 ppm STEL: 540 mg/m3
Appropriate engineering controls Engineering Controls
Showers Eyewash stations Ventilation systems.
Individual protection measures, such as personal protective equipment Eye/face protection
No special technical protective measures are necessary.
Skin and body protection
No special technical protective measures are necessary.
Respiratory protection
If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations.
General Hygiene Considerations
Handle in accordance with good industrial hygiene and safety practice.
9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Appearance
Liquid No information available
Odor
Color
No information available
Odor threshold
Property pH Melting point/freezing point Boiling point / boiling range Flash point Evaporation rate Flammability (solid, gas) Flammability Limit in Air Upper flammability limit: Lower flammability limit: Vapor pressure Vapor density Specific Gravity Water solubility Solubility in other solvents Partition coefficient Autoignition temperature Decomposition temperature Kinematic viscosity Dynamic viscosity
Values 9.5-11.00 No information available 96 No information available No information available No information available
Remar ks •Met hod
Slight, faint ammonia odor No information available
No information available No information available No information available No information available 1.08 No information available No information available No information available No information available No information available No information available No information available
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Explosive properties Oxidizing properties
No information available No information available
Other Information Softening point Molecular weight VOC Content (%) Density Bulk density
No information available No information available No information available No information available No information available
10. STABILITY AND REACTIVITY Reactivity No data available Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Extremes of temperature and direct sunlight. Incompatible materials Incompatible with strong acids and bases. Incompatible with oxidizing agents. Chlorinated compounds. Hazardous Decomposition Products Nitrogen oxides (NOx). Carbon monoxide. Carbon dioxide (CO2). Ammonia. Chlorine. Aldehydes.
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11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure No data available
Product Information Inhalation
May cause irritation of respiratory tract. Toxic by inhalation. Immediate medical attention is required.
Eye contact
Severely irritating to eyes.
Skin Contact
Repeated or prolonged skin contact may cause allergic reactions with susceptible persons. Immediate medical attention is required.
Ingestion
Harmful if swallowed. May cause drowsiness or dizziness. Seek immediate medical attention if inhaled.
Chemical Name Aromatic Alcohol
Oral LD50 = 1230 mg/kg ( Rat )
Dermal LD50 = 2 g/kg ( Rabbit )
Inhalation LC50 = 8.8 mg/L ( Rat ) 4 h
Colloidal Silica
> 5000 mg/kg ( Rat )
> 2000 mg/kg ( Rabbit )
> 2.2 mg/L ( Rat ) 1 h
Poly-Oxy Amine
= 242 mg/kg ( Rat )
= 360 mg/kg ( Rabbit )
-
m-Xylylenediamine 1477-55-0 Glycol Ether
= 660 mg/kg ( Rat )
= 2 g/kg ( Rabbit )
= 700 ppm ( Rat ) 1 h
= 5000 mg/kg ( Rat )
= 13 g/kg ( Rabbit )
> 7559 ppm ( Rat ) 6 h
Information on toxicological effects Symptoms
No information available.
Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization Germ cell mutagenicity Carcinogenicity Chemical Name Colloidal Silica
Reproductive toxicity STOT - single exposure STOT - repeated exposure Aspiration hazard
No information available. No information available. No information available. ACGIH -
IARC Group 3
NTP Reasonably Anticipated
OSHA X
No information available. No information available. No information available. No information available.
Numerical measures of toxicity - Product Information The following values are calculated based on chapter 3.1 of the GHS document . 1356 mg/kg ATEmix (oral) 2317 mg/kg ATEmix (dermal) 3500 mg/l ATEmix (inhalation-gas) ATEmix (inhalation-dust/mist) 7.5 mg/l 19 mg/l ATEmix (inhalation-vapor)
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12. ECOLOGICAL INFORMATION Ecotoxicity Harmful to aquatic life with long lasting effects Chemical Name Aromatic Alcohol
Algae/aquatic plants 35: 3 h Anabaena variabilis mg/L EC50
Colloidal Silica
440: 72 h Pseudokirchneriella subcapitata mg/L EC50 -
Glycol Ether
Fish Crustacea 10: 96 h Lepomis macrochirus mg/L 23: 48 h water flea mg/L EC50 LC50 static 460: 96 h Pimephales promelas mg/L LC50 static 5000: 96 h Brachydanio rerio mg/L 7600: 48 h Ceriodaphnia dubia LC50 static mg/L EC50 4600 - 10000: 96 h Leuciscus idus 23300: 48 h Daphnia magna mg/L mg/L LC50 static 20.8: 96 h EC50 Pimephales promelas g/L LC50 static
Persistence and degradability No information available. Bioaccumulation No information available. Chemical Name Aromatic Alcohol
Partition coefficient 1.1
Glycol Ether
-0.437
Other adverse effects
No information available
13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Contaminated packaging
Do not reuse container.
14. TRANSPORT INFORMATION DOT
Not regulated
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15. REGULATORY INFORMATION International Inventories TSCA DSL/NDSL EINECS/ELINCS ENCS IECSC KECL PICCS AICS
Complies Complies Does not comply Complies Complies Complies Complies Complies
Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances
US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Acute health hazard Chronic Health Hazard Fire hazard Sudden release of pressure hazard Reactive Hazard
No No No No No
CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material
US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals U.S. State Right-to-Know Regulations Chemical Name Aromatic Alcohol
New Jersey -
Massachusetts X
Pennsylvania X
Colloidal Silica
X
X
X
m-Xylylenediamine 1477-55-0 Glycol Ether
X
X
X
X
X
X
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16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION NFPA
Reactivity 0
Flammability 0
Physical hazards 0
Issue Date Revision Date Revision Note No information available
Physical and Chemical HMIS Properties Personal protection X
Health hazards 0
05-Jun-2016 06-Jun-2016
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet
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