MATERIAL SAFETY DATA SHEET Section 1 - Product Identification and Company Name Product Name: Sigma Marine Fish Powder Fish Powder Fertilizer N – P – K / 6 – 1 – 0.5 Product Use: Soil amendment / fertilizer Date Prepared: September 13, 2009 MSDS No. MS1610 Manufacturer: Sigma Marine Products India Kolkata-700027, West Bengal, India U.S. Office Sigma Marine Products, Ltd. P.O. Box 4679 El Dorado Hills, Ca. 95762 USA Telephone: 530-558-4004 Fax: 530-672-6442 Section 2 - Ingredient & Composition Ingredients * CAS # Component CAS # NIOSH Registered Anchovies, Sardines, Mackerel and N/A Not registered other pelagic fish *The only ingredient (fish) used to prepare this product is not listed or restricted by EPA and OSHA. Section 3 - Hazard Identification Notwithstanding its low to nil toxicity, upon its contact or ingestion certain sensitive individuals may develop symptoms similar to an allergic reaction, which might include slight or considerable eye, skin, lung and gastrointestinal tract irritation with potential accompanying nausea, vomiting or diarrhea. Section 4 - Potential Health Effects and First Aid Inhalation

Eye contact Skin Contact Ingestion

In case of inhalation of fumes from overheating or combustion, move to fresh air. If needed, seek medical attention. Inhalation of dust may aggravate asthma in susceptible individuals. In case of dust or granules in the eyes, flush thoroughly with running water. Wash thoroughly with soap and water Give plenty of water to drink and provoke vomiting. If needed, call a doctor

Section 5 - Fire Fighting Measures Flashpoint and Method Extinguishing Media Explosion Hazard Special Fire Fighting Procedures Fire Fighting Procedures Unusual Fire and Explosion Hazards Fire Fighting Equipment Flammable Limits

N/A *Water, CO2, dry chemical foam High airborne dust concentrations have the potential for explosion *Water will cause product to putrefy and eventually reheat Treat as class A Moderate fire hazard when exposed to heat or flame. Can react with oxidizing material. Could heat and ignite spontaneously depending upon moisture and oil content Wear self-contained breathing apparatus to fight large fires N/A

Section 6 - Accidental Release Sweep up, scoop or vacuum and place in appropriate waste disposal container. If large spill, collect by sweeping or shoveling ensuring that the spilled material does not enter sewers, wells or watercourse. Product will promote algae growth which may degrade water quality and taste. Avoid contact with skin, eyes, or clothing. Wash thoroughly with soap and water after handling. Avoid dusting or misting conditions during cleanup. If material is uncontaminated, collect and reuse as recommended for product. If contaminated, put in appropriate container and dispose. Make sure disposal complies with local regulations. Section 7 - Handling and Storage Handling Storage

Containers Carcinogenetic Effects of Exposure Ecological Information

See label. Do not ingest. Wash hands with soap and water after handling product. Store in a cool, dry and shaded area away from incompatible materials and heat sources. Store away from feed and foodstuffs, as well as household cleaning products Avoid container breakage; keep away from sparks, flames and excessive heat None known Avoid inhalation or contact with skin, eyes, or clothing Keep out of lakes, streams or ponds

Section 8 - Exposure Controls and Personal Protection Engineering Controls

Respiratory Protection

Eyes and Face Protection

Ventilation and personal protection are recommended whenever dust levels are high or product dos not remain intact. Running water should be available nearby in case material gets in eyes. If airborne dust levels are high or product does not remain intact, use a combination of engineering controls, such as ventilation, and personal protection, such as an approved respirator to reduce exposures to acceptable levels Goggles Recommended. Dust Mask with organic vapor filter

Skin Other Protective Clothing or Equipment: Work/Hygienic Practices

None required for normal use. If prolonged or repeated use irritates skin, wear neoprene or PVC gloves. Normal work clothing Open wounds should be kept clean and suitably protected

Section 9 - Ecological Information Other Concerns Persistence and Degradability Aquatic Toxicity

Keep out of lakes, streams or ponds. Keep out of reach of children and pets Fish powder is minimally soluble in water and biodegradable. None Known

Section 10 – Physical/Chemical Characteristics Physical State: Appearance Color Odor pH Density

Solid Granular or powder Dark brown Fishy (1:2 with Water) 5.5 – 6.5 38 - 40 lbs./ft³

Boiling Point Vapor Pressure: Solubility Melting point Evaporation rate Specific gravity

Not Applicable Not applicable 20 – 25% Not Applicable Not applicable 0.480-0.640 g/mL

Section 11 - Stability and Reactivity Chemical Stability Conditions to Avoid Incompatible Materials

Stable N/A None Known

Hazardous polymerization Hazardous Decomposition Products

No None Known

Section 12 - Toxicological Information Acute and Chronic Toxicity Carcinogenicity, Embrotoxicity, Teratogenicity, Mutagenicity, Reproductive Effects General Comments

No data None known Possible nausea, skin or eye irritation. Inhalation of dust may aggravate asthma. Eye contact with product may cause irritation, flush eyes with water as soon as possible.

Section 13 - Disposal Consideration Disposal must be in accordance with Federal, State, and Local regulations. The disposal information contained herein cannot be warranted by Sigma Marine Products India or Sigma Marine Products, Ltd. (USA) as correct in all cases. Because of particular or exceptional conditions or circumstances, or additional information or measures may be required or desirable. The product user may want to consult the proper state and federal authorities.

Section 14 - Transport Information Department of Transportation (DOT) DOT (HAZMAT) Proper Shipping Name: ID # U.S. Surface Freight Classification

Not DOT regulated Fish Powder – Does not include antioxidant * UN2216 9

DOT Label

Class 9

Pollutant N/A Category Group # N/A CHRIS Code N/A * DOT shipping requirements only are applicable to this product when transported in bulk by vessel. Section 15 - Regulatory Information Contact local authorities for proper disposal of large quantities of unused product Other Information The information contained in this MSDS is provided without warranty of any kind, express or implied. The information contained herein is made available solely for consideration, investigation, and verification by the original recipients hereof. Users should consider this information only as a supplement to other information gathered by or available to them. Users should make independent determinations of the suitability and completeness of information from all sources to assure proper use and disposal of these materials for the safety and health of employees, customers, and the environment. The information provided herein is a compilation of known or suspected information about the materials from various sources and is offered for the benefit and convenience of product customers and handlers. Further the information is SPECIFICALLY NOT WARRANTED by Sigma Marine Products India or Sigma Marine Products, Ltd. (USA) either to its comprehensiveness, correctness, sufficiency, or scientific accuracy. This hazard information is not a substitute for risk assessment under actual conditions of use. Users have the responsibility to keep currently informed on chemical hazard information, to design and update their own programs, and to comply with all applicable national, federal, state, and local laws and regulations regarding safety, occupational health, right to know, and environmental protection.