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Code No: 210853 II-B.Tech. I-Semester Supplementary Examinations, May/June-2004 ORGANIC CHEMISTRY (Chemical Engineering) Max. Marks: 70 Answer any FIVE questions All questions carry equal marks ---

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Time: 3 Hours

How to explain acidic properties of dicarboxylic acid using Inductive effect Explain the following applications of Inductive effect (i) Basic characteristics of amines (ii) Formation of esters

2.a) b)

Discuss about hydroboration with reaction mechanism. Describe the Clemenson’s reduction.

3.

Show the reaction mechanisms of the following reactions: (i) Gatterman reaction (ii) Fittig reaction (iii) Kolbes reaction.

4.a)

Draw the structure of the optical isomers of lactic acid and assign R and S notation with the help of sequence rule. How many asymmetric carbon atoms are present in tartaric acid? How many active forms of tartaric acids exist?

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b)

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5.

Write a note on conformational analysis of cyclothexane.

6.a)

With an example, explain how interconversion of a ketose into an aldose is possible. Elucidate the ring structure of fructose.

b)

What happens when pyrrole is heated with bromine? How is Quinoline obtained by Skraup synthesis?

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7.a) b)

What are dyes? How they are classified? Explain the classification of dye, based on their chemical structure.

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8.a) b) c)

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Code No: 210853 II-B.Tech. I-Semester Supplementary Examinations ...

Code No: 210853. II-B.Tech. I-Semester Supplementary ... b) How is Quinoline obtained by Skraup synthesis? 8.a) What are dyes? b) How they are classified?

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