D3/UG2/7/A16 Reg. No

St. Joseph’s College of Arts & Science (Autonomous) St. Joseph’s College Road, Cuddalore – 607001 CH305S – INORGANIC CHEMISTRY - II

Time : 3 hrs

Max Marks :75 SECTION – A (20X1=20) Answer ALL Questions

I. Choose the correct answer 1. The spot test reagent for Nickel is _______. a) Cupferron b) DMG c) Aluminon

d) Alizarin

2. Which one of the following is the protic solvent? a) CH3CN b) HCl c) CCl4

d) DMSO

3. SiO2 is_______ a) Liquid

d) Semisolid

b) Gas

c) Solid

4. Example for interstitial carbide. a) WC b) SiC c) B4C 5. Marshall’s acid a) H2SO4

b) H2S2 O8

c) H2SO5

d) CaC2 d) H2SO3

6. Basic character of PH3 is a) Greater than NH3 c) Equal to NH3

b) Less than NH3 d) Equal to NaOH

7. Structure of XeF4 a) Tetrahedral c) Square planar

b) Octahedral d) T shape

8. The noble gas which does not have eight electrons in outermost orbital a) He b) Xe c) Ar d) Ne

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D3/UG2/7/A16 9. Number of valence electrons in halogens a) 8 b) 6 c) 4 10. Uranium hexafluoride does react with a) Oxygen c) Carbon dioxide

d) 7

b) Nitrogen d) Water

II. Fill up the blanks 11. Autodissociation of liquid ammonia is _________than that of water. 12. Framework minerals are called ______________ 13. N3H + 4H2

_____________

14. ____________is the active compound in bleaching powder. 15. The predominate mineral of titanium is _____________ III. Match the following 16. Nessler’s reagent

-

He

17. Vulcanisation

-

F

18. Caro’s acid

-

KI + HgCl2

19. Air ship

-

CS2

20. Electronegativity

-

H2SO5

SECTION – B (10X2=20) Answer any TEN Questions 21. What are amphoteric solvents? 22. What is meant by common ion effect?

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D3/UG2/7/A16 23. What is mean by catenation? 24. What are orthosilicates? 25. Draw the structure of BiH3 26. List out the nitrogen group elements. 27. Define clathrates. 28. What is the shape and hybridization of XeF2? 29. What are interhalogen compounds? 30. Give any two uses of noble gases. 31. What is meant by smelting? 32. What is the general electronic configuration of d-block elements? SECTION- C (5X7=35) Answer any FIVE Questions 33. a) Explain the reactions involved in the separation and identification of Fe2+, Cu2+ and Al3+ ions. b) Explain different types of solvents with suitable examples.

(4) (3)

34. a) Complete and balance the following equations. (3) ? i) CaC2 + H2O ii) Be2C + H2O ? iii) SiO2 + C ? b) Explain double decomposition reaction with suitable example. (4) 35. a) Explain the anomalous behaviour of oxygen. b) Draw and explain the structure of H2S2O7.

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(3) (4)

D3/UG2/7/A16 36. a) Discuss the similarities between H2O and HF b) Give the reason for placing noble gases in zero group.

(4) (3)

37. a) Explain the preparation and uses of V2O5. (4) b) How metals are purified in Zone refining process? Explain. (3) 38. a) Draw and explain the structures of PCl5 and PCl3. b) Compare the properties of carbon and silicone.

(4) (3)

39. a) Give brief note on ion-dipole-dipole interaction. b) Explain the preparation and uses of UF6.

(4) (3)

*************

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INORGANIC CHEMISTRY - II - 04 16.pdf

Uranium hexafluoride does react with. a) Oxygen b) Nitrogen. c) Carbon ... (4). Page 3 of 4. Main menu. Displaying INORGANIC CHEMISTRY - II - 04 16.pdf.

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