Set No: Code No: RR-10104.

1

I-B.Tech. Regular Examinations, May/June-2004 APPLIED CHEMISTRY (Civil Engineering)

Max. Marks: 80 Answer any FIVE questions All questions carry equal marks ---

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Time: 3 Hours

Discuss the importance of design and material selection in corrosion control. Distinguish between dry corrosion and wet corrosion.

2.a) b)

What are the constituents of paint? Mention their functions. Write a note on vitreous enamels.

3.a) b)

How is aluminium anodized? What are the applications of such coatings. What is caustic embrittlement.

4.a) b)

How are the following polymers obtained? PVC, Teflon and polymethacrylate. Define the following terms with one example each (i) Monomer (ii) Degree of polymerisation.

5.a)

What are the troubles introduced by the use of hard water in a boiler. Explain the reasons. Write the requirements of a good drinking water.

6.a) b)

With a neat diagram explain the ion exchange process for the purification of water. Derive the relationship between parts per million and milligram per litre. How does tricalcium silicate react with water? Write the corresponding equation. What is Portland cement? Why is it called so? Give its composition.

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7.a) b)

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b)

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1.a) b)

What are refractories? How are they classified. Give examples. What is meant by thermal spalling? How is it reduced?

Aj

8.a) b)

@&@&@

Set No: Code No: RR-10104.

2

I-B.Tech. Regular Examinations, May/June-2004 APPLIED CHEMISTRY (Civil Engineering)

Max. Marks: 80 Answer any FIVE questions All questions carry equal marks ---

.in

Time: 3 Hours

Give one example of chemical corrosion and electrochemical corrosion and explain the mechanism.

2.a)

Explain the protective coatings you would choose for; steel; cast Iron and concrete pipe. Give reasons for your answer. Write a note on Distempers.

b) 3.a)

b)

or ld

1.

Discuss the corrosion occurring in the following: (i) Crack in the metal (ii) Wire fence. (iii) Rivetted joints. What is meant by phosphating of steel?

Distinguish between thermoplastics and thermosetting plastics. Explain the term vulcanisation.

5.a) b)

Give an account of fabrication of plastics by injection moulding. Classify the following into thermoplastics and thermosetting plastics. (i) Cellulose acetate. (ii) Nylon 6,6. (iii) Bakelite. (iv) PVC.

6.a) b)

How is permanent hardness of water determined by alkali titration method? 100 ml of a sample of water has a hardness equivalent to 12.5 ml of 0.08N MgSO4. What is the hardness of water.

7.a) b)

What are the characteristics of a good refractory. Write a note on thermal insulators.

Aj

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4.a) b)

8.a) b)

Discuss the manufacture of Portland cement by wet process. Write a note on setting and hardening of lime. @&@&@

Set No: Code No: RR-10104.

3

I-B.Tech. Regular Examinations, May/June-2004 APPLIED CHEMISTRY (Civil Engineering) Time: 3 Hours

2.a)

b)

.in

b)

Answer any FIVE questions All questions carry equal marks --what an account of procedure adopted for cleaning the surface prior to coating on them. What is a lacquer? What are its ingredients. Write notes on : (i) Corrosion fattigue. (ii) Corrosion inhibitors. What happens when a metallic rod is partially buried under earth?

or ld

1.a)

Max. Marks: 80

Explain the sacrificial anode method of corrosion control. Write a note on emulsion paints.

4.a) b)

Write down the factors affecting electroplating. Write notes on: (i) Stress Corrosion. (ii) Soil Corrosion.

5.a)

Explain clearly the function of the following additives when added to polymers. (i) Plasticizers. (ii) Fillers and (iii) Foaming agent. How are the following polymers prepared? (i) Polymethacrylate. (ii) Thiokol.

b)

Explain with a neat sketch the various steps in the treatment of water for municipal supply. What are scales and sludges? How are they formed?

nt

6.a)

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3.a) b)

b)

What is an insulator? How are they classified. Give examples. Write any five disadvantages of using Refractory materials.

Aj

7.a) b) 8.a)

b)

Write briefly on the classification of lime, indicating their composition, properties and uses. Write the composition of Portland cement. @&@&@

Set No: Code No: RR-10104.

4

I-B.Tech. Regular Examinations, May/June-2004

(Civil Engineering) Time: 3 Hours

b) 2.a) b)

Max. Marks: 80

Answer any FIVE questions All questions carry equal marks --What is Galvanic corrosion? When zinc and copper are electrically connected and exposed to an electrolyte which metal will get corroded? Why? Explain the mechanism. What is meant by passivation?

or ld

1.a)

.in

APPLIED CHEMISTRY

Write notes on : (i) Metal Cladding. (ii) Cementation. Distinguish between galvanising and tinning.

How do paints differ from varnishes. Explain the method of controlling corrosion by modifying the environment.

4.a) b)

Write a note on compounding of plastics. Give the composition, properties and engineering applications of silicone resins.

5.a) b)

Explain the changes caused in the characteristics of rubber due to vulcanisation. Explain the principle of estimation of total hardness of water using EDTA method.

6.a) b)

Compare the lime soda process with zeolite process of water softening. Calculate the quantity of lime and soda required for softening 1,00,000 litres of water containing the following impurities per litre. Ca(HCO3)2 = 8.1 Mg; CaSO4 = 13.6 Mg. Mg(HCO3)2 = 7.3 Mg; MgSO4 = 12.0 Mg. Nacl = 4.6 Mg; Silica = 1.2 Mg.

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3.a) b)

Write any three important characteristics of insulators. Explain the different types of refractories.

8.a) b)

Discuss the salient features of the manufacture of lime and explain the reactions. What is the difference between the setting of lime and the setting of cement.

Aj

7.a) b)

@&@&@

Set No Accounts

Crack in the metal · (ii) · Wire fence. (iii) Rivetted joints. b) What is meant by phosphating of steel? 4.a) Distinguish between thermoplastics and thermosetting ...

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